女人不愛，男人使壞
知名的兩性作家、電視名嘴、偷心界聖字輩的PS男、 夏和杰（藍正龍飾）為了追求第一名模阿曼達（白歆惠飾），大鬧電影首映會會場，被法院判處158小時的社會勞動役。
夏和杰被分派到天使幼稚園。幼稚園的老師碰巧是夏和杰小時候的同學、馬小茜（隋棠飾）。夏和杰沒認出馬小茜就是小時候老被他欺負的鋼牙妹！馬小茜愛面子也沒說穿這段往事。如今仇人相見，小茜逮到機會就惡整夏和杰，但卻意外地在報復的過程中愛上了花心的和杰！
在某天開娃娃車送小朋友回家的途中，夏和杰意外跟豪門第二代孟成恩（溫昇豪飾）發生衝突，自大的夏和杰槓上了狂傲的孟成恩！孟成恩為了證明自己高人一等，對夏和杰全面宣戰！只要是夏和杰想要的東西，他通通都要搶走，包括第一名模阿曼達！
在這場名模的爭奪戰中，孟成恩認識了小茜。他被小茜的純真所吸引，轉而追求小茜。夏和杰雖然贏得阿曼達的芳心，但是此刻他卻發現自己真正喜歡的人是馬小茜。不過此時的夏和杰已經難以回頭、牽絆他的除了阿曼達的真情、還有阿曼達的私生子小陀螺（小小彬飾）對他的信任及感情！小茜雖然喜歡和杰，但她不願意介入夏和杰與阿曼達的戀情，她選擇接受了孟成恩的感情，答應了孟成恩的求婚…
「PS男」跟「鋼牙妹」的戀情會在遺憾中劃下句點？
還是王子、公主最後過著幸福快樂的生活？
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Kang Suk Ho is an ordinary lawyer who decides to take up a job at the nearby high school. After seeing the conditions of the school and the poor grades all the students have, Suk Ho decides to create a special class promising admission to the most prestigious college in Korea, "Chun-Ha-Dae University." Five of the most laziest students - Hwang Baek Hyun, Gil Pul Ip, Na Hyun Jung, Hong Chan Doo, and Oh Bong Goo join the class to in order to prove that they can do it with hard work and dedication.